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Unit 3: Chemical Bonding and Molecular Structure — Online MCQ Test

CHEMISTRY · NEET (All) · NEET
Practice Unit 3: Chemical Bonding and Molecular Structure with a free chapter-wise online MCQ test. This chapter covers: Kossel - Lewis approach to chemical bond formation the concept of ionic and covalent bonds. Ionic Bonding: Formation of ionic bonds factors affecting the formation of ionic bonds;.... AI-generated questions from basic to board-exam level, with instant results and explanations.

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Unit 3: Chemical Bonding and Molecular Structure — Important Questions & Answers

Given below are two statements: Statement I: A hypothetical diatomic molecule with bond order zero is quite stable. Statement II: As bond order increases, the bond length increases.
  • A. Both statement I and Statement II are true
  • B. Both statement I and Statement II are false
  • C. Statement I is true but Statement II is false
  • D. Statement I is true but Statement II is true
Answer: B. Both statement I and Statement II are false
Bond order zero implies the molecule is unstable. As bond order increases, bond length decreases. Both statements are false.
Given below are two statements: Statement I: A hypothetical diatomic molecule with bond order zero is quite stable. Statement II: As bond order increases, the bond length increases. In the light of the above statements, choose the most appropriate answer from the options given below:
  • A. Both statement I and Statement II are true
  • B. Both statement I and Statement II are false
  • C. Statement I is true but Statement II is false
  • D. Statement I is true but Statement II is true
Answer: B. Both statement I and Statement II are false
Bond order 0 implies the molecule is unstable. As bond order increases, bond length decreases (inversely proportional). Both statements are false.
Match the List -I with List-II. List-I: (A) XeO₃, (B) XeF₂, (C) XeOF₄, (D) XeF₆. List-II: (I) sp³d; linear, (II) sp³; pyramidal, (III) sp³d³; distorted octahedral, (IV) sp³d²; square pyramidal.
  • A. A-II, B-I, C-IV, D-III
  • B. A-II, B-I, C-III, D-IV
  • C. A-IV, B-II, C-III, D-I
  • D. A-IV, B-II, C-I, D-III
Answer: A. A-II, B-I, C-IV, D-III
XeO₃ is sp³ pyramidal (A-II); XeF₂ is sp³d linear (B-I); XeOF₄ is sp³d² square pyramidal (C-IV); XeF₆ is sp³d³ distorted octahedral (D-III).
Identify the correct orders against the property mentioned: A. H2O > NH3 > CHCl3 - dipole moment B. XeF4 > XeO3 > XeF2 – number of lone pairs on central atom C. O–H > C –H > N–O – bond length D. N2 > O2 > H2 – bond enthalpy Choose the correct answer from the options given below:
  • A. A, D only
  • B. B, D only
  • C. A, C only
  • D. B, C only
Answer: A. A, D only
A is correct (Dipole moments: 1.85D, 1.47D, 1.04D). D is correct (Bond enthalpies of N2 are much higher due to triple bond).
Predict the correct order among the following VSEPR repulsion strengths:
  • A. lone pair- lone pair > lone pair - bond pair > bond pair - bond pair
  • B. lone pair - lone pair > bond pair - bond pair > lone pair - bond pair
  • C. bond pair - bond pair > lone pair - bond pair > lone pair - lone pair
  • D. lone pair - bond pair > bond pair - bond pair > lone pair - lone pair
Answer: A. lone pair- lone pair > lone pair - bond pair > bond pair - bond pair
According to VSEPR theory, the order of repulsion is: lp-lp > lp-bp > bp-bp.