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Unit 6: Thermo Dynamics — Online MCQ Test

CHEMISTRY · CLASS 11 INTERMEDIATE 1 YEAR · Telangana State Board
Practice Unit 6: Thermo Dynamics with a free chapter-wise online MCQ test. This chapter covers: This chapter details system types state functions first second third laws of thermodynamics enthalpy heat capacity and Hess law. Students examine spontaneity Gibbs free energy chan.... AI-generated questions from basic to board-exam level, with instant results and explanations.

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Unit 6: Thermo Dynamics — Important Questions & Answers

Which of the following is an example of an open system?
  • A. A sealed flask of water
  • B. A pressure cooker with closed lid
  • C. A human body
  • D. A thermos flask
Answer: C. A human body
A human body exchanges both matter and energy with the surroundings, so it is an open system.
Which of the following is a state function?
  • A. Heat
  • B. Work
  • C. Internal energy
  • D. Path length
Answer: C. Internal energy
Internal energy depends only on the state of the system, not on the path taken.
For an exothermic reaction at constant pressure, the enthalpy change is:
  • A. Positive
  • B. Negative
  • C. Zero
  • D. Always equal to heat capacity
Answer: B. Negative
In an exothermic reaction, heat is released by the system, so ΔH is negative at constant pressure.
For a reaction with ΔH = +40 kJ mol⁻¹ and ΔS = +100 J mol⁻¹ K⁻¹, at what temperature does spontaneity begin? (Use T = ΔH/ΔS)
  • A. 200 K
  • B. 300 K
  • C. 400 K
  • D. 500 K
Answer: C. 400 K
Convert ΔH to 40000 J mol⁻¹. Then T = 40000/100 = 400 K, which is the threshold temperature.
Which of the following is the correct relation between heat absorbed at constant pressure and enthalpy change?
  • A. q_p = ΔU
  • B. q_p = −ΔH
  • C. q_p = ΔH
  • D. q_p = ΔG
Answer: C. q_p = ΔH
At constant pressure, the heat absorbed or released by the system equals the enthalpy change.