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Unit 3: Electro Chemistry and Chemical Kinetics — Online MCQ Test

CHEMISTRY · CLASS 12 INTERMEDIATE 2 YEAR · Telangana State Board
Practice Unit 3: Electro Chemistry and Chemical Kinetics with a free chapter-wise online MCQ test. This chapter covers: This chapter covers Nernst equation Kohlrausch Law conductance battery types rate laws reaction orders Arrhenius equation activation energy and collision theory.. AI-generated questions from basic to board-exam level, with instant results and explanations.

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Unit 3: Electro Chemistry and Chemical Kinetics — Important Questions & Answers

What does the Nernst equation relate in an electrochemical cell?
  • A. Cell potential and concentration of ions
  • B. Cell potential and temperature only
  • C. Resistance and conductance
  • D. Rate constant and activation energy
Answer: A. Cell potential and concentration of ions
The Nernst equation is used to calculate the electrode or cell potential under non-standard conditions, especially when ion concentrations change.
Which law states that the molar conductance of an electrolyte at infinite dilution is the sum of the individual ionic conductances?
  • A. Faraday's law
  • B. Kohlrausch's law
  • C. Ohm's law
  • D. Raoult's law
Answer: B. Kohlrausch's law
Kohlrausch's law of independent migration of ions explains that at infinite dilution, each ion contributes independently to molar conductance.
Which quantity is obtained from the slope of a plot of log k versus 1/T for a reaction?
  • A. Heat of reaction
  • B. Activation energy
  • C. Equilibrium constant
  • D. Order of reaction
Answer: B. Activation energy
According to the Arrhenius equation, a plot of log k versus 1/T gives a straight line whose slope is related to activation energy.
Which statement is correct about activation energy?
  • A. It is the energy released in a reaction
  • B. It is the minimum energy required for effective collision
  • C. It is always zero for all reactions
  • D. It is the difference between products and reactants only
Answer: B. It is the minimum energy required for effective collision
Activation energy is the minimum energy that reacting molecules must possess to form the activated complex and undergo reaction.
The rate constant of a reaction increases four times when temperature is raised from T to T + 10 K. This indicates that the reaction has:
  • A. Very low activation energy
  • B. Very high activation energy
  • C. Zero order
  • D. Negative activation energy
Answer: B. Very high activation energy
A large increase in rate constant with a small rise in temperature suggests that the reaction is highly sensitive to temperature, which is characteristic of a high activation energy.