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CBSE(NCERT) · Grade 12 · Chemistry

CBSE(NCERT) GRADE 12 CHEMISTRY 2024 SET 5

50 questions from this Grade 12 Chemistry paper. Log in as a Grade 12 student to view solutions.

Q1 mcq 1 mark
Which of the following does not show variable oxidation states ?
  • A. Fe
  • B. Cu
  • C. Mn
  • D. Sc

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Q2 mcq 1 mark
The type of isomerism shown by the complex [CoCl2 (en)2]+ is :
  • A. Ionisation isomerism
  • B. Geometrical isomerism
  • C. Linkage isomerism
  • D. Coordination isomerism

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Q3 mcq 1 mark
Which of the following is diamagnetic in nature ? [ Atomic number : Co = 27 ]
  • A. Co3+, octahedral complex with strong field ligand
  • B. Co3+, octahedral complex with weak field ligand
  • C. Co3+, in a square planar complex
  • D. Co3+, in a tetrahedral complex

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Q4 mcq
Consider the following reaction : The major product of the reaction is :

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Q5 mcq 1 mark
Which one of the following compounds has the lowest pKa value ?
  • A. p-Cresol
  • B. p-Nitrophenol
  • C. m-Nitrophenol
  • D. 2,4,6-Trinitrophenol

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Q6 mcq 1 mark
(CH3)2CH O CH3 when treated with HI gives :
  • A. (CH3)2CH I + CH3OH
  • B. (CH3)2CH OH + CH3 I
  • C. (CH3)2CH I + CH3 I
  • D. (CH3)2CH OH + CH3OH

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Q7 mcq
Which of the following compounds on treatment with benzene sulphonyl choride forms an alkali-soluble precipitate ?
  • A. CH3CONH2
  • B. (CH3)3N
  • C. (CH3)2NH
  • D. CH3CH2NH2

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Q8 mcq 1 mark
The increasing order of basic strength of CH3NH2 (I), (CH3)2NH (II), (CH3)3N (III) and C6H5NH2 (IV) in aqueous medium is :
  • A. IV < III < I < II
  • B. II < I < IV < III
  • C. I < II < III < IV
  • D. II < III < I < IV

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Q9 mcq
The vitamin which plays an important role in coagulating blood is :
  • A. Vitamin A
  • B. Vitamin E
  • C. Vitamin D
  • D. Vitamin K

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Q10 mcq
When a catalyst increases the rate of a chemical reaction, then the rate constant (k) :
  • A. remains constant
  • B. decreases
  • C. increases
  • D. may increase or decrease depending on the order of the reaction

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Q12 mcq
During the electrolysis of aqueous NaCl, the cathodic reaction is :
  • A. Oxidation of Cl ion
  • B. Reduction of Na+ ion
  • C. Oxidation of H2O
  • D. Reduction of H2O

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Q13 mcq
Assertion (A) : Addition of ethylene glycol to water lowers its freezing point. Reason (R) : Ethylene glycol is insoluble in water due to lack of its ability to form hydrogen bonds with water molecules.
  • A. Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A).
  • B. Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of the Assertion (A).
  • C. Assertion (A) is true, but Reason (R) is false.
  • D. Assertion (A) is false, but Reason (R) is true.

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Q14 short answer
Assertion (A) : Order of reaction and molecularity are always same for complex reactions. Reason (R) : Order is determined experimentally and molecularity is applicable only for elementary reactions.

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Q15 short answer
Assertion (A) : The boiling point of ethanol is higher than that of dimethyl ether. Reason (R) : Ethanol molecules are associated through hydrogen bonding whereas in dimethyl ether, it is not possible.

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Q16 short answer
Assertion (A) : Aniline does not undergo Friedel-Crafts reaction. Reason (R) : Friedel-Crafts reaction is an electrophilic substitution reaction.

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Q17 short answer 2 marks
(a) What type of nucleophilic substitution (SN1 or SN2) occurs in the hydrolysis of 2-Bromobutane to form ( )-Butan-2-ol ? Give reason.

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Q18 short answer 1 mark
(b) What happens when chlorobenzene and methyl chloride are treated with sodium metal in dry ether ?

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Q19 short answer 1 mark
(a) (i) Reimer-Tiemann reaction

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Q20 short answer 1 mark
(a) (ii) Kolbe's reaction

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Q21 short answer 1 mark
(b) Name the reagent used in the bromination of phenol to form 2,4,6-Tribromophenol.

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Q22 short answer 1 mark
(a) Benzoic acid to Benzaldehyde

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Q23 short answer 1 mark
(b) Ethanal to Propanone

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Q24 short answer 3 marks
A first-order reaction is 25 complete in 40 minutes. Calculate the value of rate constant. In what time will the reaction be 80 complete ? Given : log 2 = 0·30, log 3 = 0·48, log 4 = 0·60, log 5 = 0·6925.

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Q24 short answer 1 mark
(c) Acetophenone to Benzoic acid

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Q25 short answer 1 mark
(d) Bromobenzene to 1-Phenylethanol

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Reading Passage

The involvement of (n 1)d electrons in the behaviour of transition elements impart certain distinct characteristics to these elements. Thus, in addition to variable oxidation states, they exhibit paramagnetic behaviour, catalytic properties and tendency for the formation of coloured ions. The transition metals react with a number of non-metals like oxygen, nitrogen and halogens. KMnO4 and K2Cr2O7 are common examples. The two series of inner transition elements, lanthanoids and actinoids, constitute the f-block of the periodic table. In the lanthanoids, there is regular decrease in atomic size with increase in atomic number due to the imperfect shielding effect of 4f-orbital electrons which causes contraction.

Q27 short answer 1 mark
(a) Why do transition metals and their compounds act as good catalysts ?

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Q28 short answer 3 marks
Give the structures of A, B and C in the following reactions :

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Q28 short answer 1 mark
(b) What is the cause of contraction in the atomic size of lanthanoids ?

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Q29 short answer 2 marks
(c) Define lanthanoid contraction. How does it affect the atomic radii of the third transition series and the second transition series ?

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Q30 short answer 2 marks
(c) In aqueous media, which is a stronger reducing agent Cr2+ or Fe2+ and why ?

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Reading Passage

Proteins are the most abundant biomolecules of the living system. Proteins are the polymers of about twenty different -amino acids which are linked by peptide bonds. Ten amino acids are called essential amino acids. In zwitter ionic form, amino acids show amphoteric behaviour as they react both with acids and bases. On the basis of their molecular shape, proteins are classified into two types : Fibrous and Globular proteins. Structure and shape of proteins can be studied at four different levels i.e., primary, secondary, tertiary and quaternary, each level being more complex than the previous one. The secondary or tertiary structure of proteins get disturbed on change of pH or temperature and they are not able to perform their functions. This is called denaturation of proteins.

Q31 short answer 1 mark
What are essential amino acids?

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Q32 short answer 1 mark
What is meant by zwitter ionic form of amino acids?

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Q33 short answer
Give one example each for Fibrous protein and Globular protein.

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Q34 short answer 2 marks
What type of linkages hold monomers of proteins together?

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Q35 short answer
Calculate emf of the following cell at 25ºC : Zn (s) | Zn2+ (0·001M) || Cd2+ (0·1 M) | Cd (s). Given : Eº Zn2+/Zn = -0·76 V, Eº Cd2+/Cd = -0·40 V [log 10 = 1]

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Q36 short answer
Calculate the ΔrGº and log Kc for the following cell reaction : Fe (s) + Ag+ (aq) → Fe2+(aq) + Ag (s). Given : Eº Fe2+/Fe = -0·44 V, Eº Ag+/Ag = + 0·80 V, 1 F = 96500 C mol-1

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Q37 short answer
Write any two advantages of the fuel cells over primary and secondary batteries?

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Q38 short answer
How many Faradays are required for the oxidation of 1 mole of H2O to O2?

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Q39 short answer 1 mark
Write the IUPAC name of the complex [Co(H2O)(CN)(en)2]2+.

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Q40 short answer
Why do tetrahedral complexes, where the central metal ion is bonded to two different types of unidentate ligands, not exhibit geometrical isomerism?

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Q41 short answer 2 marks
Give simple chemical tests to distinguish between the following pairs of compounds : (1) (2) Pentanal and Pentan-3-one

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Q42 short answer 2 marks
Give reasons for the following : (1) In semicarbazide, only one NH2 group is involved in the formation of semicarbazone. (2) Acetaldehyde is more reactive than acetone towards addition of HCN.

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Q43 short answer 2 marks
(1) Arrange the following in decreasing order of their acidic strength : CH3COOH, O2N CH2 COOH, HCOOH (2) Name the reagent in the following reaction : CH3 CH = CH CH2 CN ? CH3 CH = CH CH2 CHO

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Q44 short answer 1 mark
Write the reaction involved in Hell-Volhard-Zelinsky reaction.

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Q45 short answer 1 mark
Why is geometrical isomerism not possible in tetrahedral complexes having two different types of unidentate ligands coordinated with the central metal ion ?

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Q46 short answer
Arrange the following complex ions in increasing order of their crystal field splitting energy (o) : [Co(NH3)6]3+, [CoF6]3-, [Co(CN)6]3-

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Q47 short answer
Write the hybridization and magnetic character of the complex [Ni(CO)4] on the basis of valence bond theory. [Atomic No. : Ni = 28]

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Q48 short answer
Out of [CoF6]3- and [Co(C2O4)3]3-, which one complex is : (i) more stable ? (ii) the high spin complex ?

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Q49 short answer
What is the difference between an ambidentate ligand and bidentate ligand ?

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Q50 short answer
Write the electronic configuration of d5 in terms of t2g and eg in an octahedral field when : (i) o > P, and (ii) o < P

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