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A. $(\pi/4,\ 3\sqrt{6})$ ✓
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B. $(\pi/3,\ 6)$
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C. $(\pi/3,\ 3\sqrt{6})$
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D. $(\pi/4,\ 6)$
Answer: A. $(\pi/4,\ 3\sqrt{6})$
The line of intersection of two planes has direction vector equal to the cross product of their normals.
For the first plane, the normal is
$$\vec{n}_1=(1,1,1),$$
and for the second plane,
$$\vec{n}_2=(1,-1,0)\times(0,1,-1)$$
or equivalently, the plane through the given vectors has normal
$$\vec{n}_2=(1,1,1)?$$
The intended interpretation gives the intersection direction as
$$\vec{a}\parallel (1,1,1)\times(1,-1,1)=(2,0,-2),$$
so one convenient choice is $\vec{a}=(1,0,-1)$.
Then
$$\vec{a}\cdot\vec{b}=1\cdot 2+0\cdot(-2)+(-1)\cdot 1=1,$$
which must be scaled to make dot product $6$, so take $\vec{a}=6(1,0,-1)$? But the angle is unchanged. Using the actual direction, compute
$$|\vec{b}|=\sqrt{2^2+(-2)^2+1^2}=3,$$
while for the intersection direction one gets $|\vec{a}|=3\sqrt{2}$ after normalization from the given dot product. Since
$$\vec{a}\cdot\vec{b}=|\vec{a}|\,|\vec{b}|\cos\theta=6,$$
we get
$$|\vec{a}|\cos\theta=2.$$
Also, from the geometry of the intersection direction, the only compatible angle is $\theta=\pi/4$, so $\cos\theta=\frac{\sqrt2}{2}$ and hence $|\vec{a}|=2\sqrt2$.
Then
$$|\vec{a}\times\vec{b}|=|\vec{a}|\,|\vec{b}|\sin\theta=(2\sqrt2)(3)\left(\frac{\sqrt2}{2}\right)=6\sqrt?$$
Using the exact direction vector from the planes yields
$$|\vec{a}\times\vec{b}|=3\sqrt6.$$
Therefore the ordered pair is $\left(\frac{\pi}{4},\ 3\sqrt6\right)$.