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Q1
mcq
1 mark
Alkenes are formed by heating alcohols with conc. H2SO4. The first step in the reaction is :
-
A.
formation of carbocation
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B.
formation of ester
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C.
protonation of alcohol molecule
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D.
elimination of water
Q2
mcq
1 mark
Polyhalogen compounds have wide application in industries and agriculture. DDT is also a very important polyhalogen compound. It is a :
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A.
greenhouse gas
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B.
fertilizer
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C.
biodegradable insecticide
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D.
non-biodegradable insecticide
Q3
mcq
1 mark
The product of the oxidation of I– with MnO4– in alkaline medium is :
-
A.
IO4–
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B.
I2
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C.
IO–
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D.
IO3–
Q5
mcq
1 mark
Out of 2-Bromobutane, 1-Bromobutane, 2-Bromopropane and 1-Bromopropane, the molecule which is chiral in nature is :
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A.
2-Bromobutane
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B.
1-Bromobutane
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C.
2-Bromopropane
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D.
1-Bromopropane
Q6
mcq
1 mark
In the Haworth structure of the following carbohydrate, various carbon atoms have been numbered. The anomeric carbon is numbered as :
Q7
mcq
1 mark
The value of Henry’s constant KH is :
-
A.
greater for gases with higher solubility
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B.
greater for gases with lower solubility
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C.
constant for all gases
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D.
not related to the solubility of gases
Q8
mcq
1 mark
Out of the following statements, the incorrect statement is :
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A.
La is actually an element of transition series.
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B.
Zr and Hf have almost identical atomic radii because of lanthanoid contraction.
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C.
Ionic radius decreases from La3+ to Lu3+ ion.
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D.
Lanthanoids are radioactive in nature.
Q9
mcq
1 mark
In an electrochemical cell, the following reaction takes place : 2Ag+(aq) + Mg (s) → 2Ag (s) + Mg2+(aq) E°cell = 2·96 V As the reaction progresses, what will happen to the overall voltage of the cell ?
-
A.
Voltage will remain constant.
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B.
It will decrease as [Mg2+] increases.
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C.
It will increase as [Ag+] increases.
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D.
It will increase as [Mg2+] increases.
Q9
mcq
What is the effect of changing concentration on the voltage of the cell ?
-
A.
Voltage will remain constant.
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B.
It will decrease as [Mg2+] increases.
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C.
It will increase as [Ag+] increases.
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D.
It will increase as [Mg2+] increases.
Q10
mcq
1 mark
Out of Ti3+, Cr3+, Mn2+ and Ni2+ ions, the one which has the highest magnetic moment is :
-
A.
Ti3+
-
B.
Cr3+
-
C.
Mn2+
-
D.
Ni2+
Q10
mcq
Out of Ti3+, Cr3+, Mn2+ and Ni2+ ions, the one which has the highest magnetic moment is : [Atomic number : Ti = 22, Cr = 24, Mn = 25, Ni = 28]
-
A.
Ti3+
-
B.
Cr3+
-
C.
Mn2+
-
D.
Ni2+
Q11
mcq
Hoffmann Bromamide degradation reaction is given by :
-
A.
CH3NO2
-
B.
CH3NH2
-
C.
CH3CONH2
-
D.
CH3CH2NH2
Q12
mcq
What amount of electric charge is required for the oxidation of 1 mole of H2O to O2 ?
Q13
short answer
Assertion (A) : Cuprous salts are diamagnetic. Reason (R) : In cuprous ion, 3d-orbitals are partially filled.
Q14
short answer
Assertion (A) : Acetanilide is more basic than aniline. Reason (R) : Acetylation of aniline results in decrease of electron density on nitrogen.
Q15
short answer
Assertion (A) : Electrolysis of aqueous NaCl gives H2 at cathode and Cl2 at anode. Reason (R) : Chlorine has higher oxidation potential than H2O.
Q16
short answer
Assertion (A) : n-Butyl chloride has higher boiling point than n-Butyl bromide. Reason (R) : C – Cl bond is more polar than C – Br bond.
Q17
short answer
2 marks
What is meant by essential amino acids ? Why are amino acids amphoteric in nature ?
Q19
short answer
2 marks
Reactant ‘A’ underwent a decomposition reaction. The concentration of ‘A’ was measured periodically and recorded in the table given below : Time/Hours [A]/M 0 0·40 1 0·20 2 0·10 3 0·05 Based on the above data, predict the order of the reaction and write the expression for the rate law.
Q19
short answer
2 marks
PtCl4 . 2KCl doesn’t give precipitate of AgCl with AgNO3 solution. Write the structural formula and IUPAC name of the complex
Q20
short answer
2 marks
The reaction between H2(g) and I2(g) was carried out in a sealed isothermal container. The rate law for the reaction was found to be : Rate = k[H2] [I2] If 1 mole of H2(g) was added to the reaction chamber and the temperature was kept constant, then predict the change in rate of the reaction and the rate constant.
Q20
short answer
2 marks
Define fuel cell. Give two advantages of fuel cell in comparison to ordinary cell.
Q21
short answer
2 marks
Write the structures of the main products of the following reactions:
Q21
short answer
2 marks
Write the structures of the main products of the following reactions: (a) 6 R – C – OH + 2Al → (b)
Q23
short answer
3 marks
Arrange the following compounds as asked: (a) in increasing order of pKb values C2H5NH2, (C2H5)2NH, C6H5NHCH3, C6H5NH2 (b) in decreasing order of boiling point C2H5OH, C2H5NH2, (CH3)2NH (c) in decreasing order of solubility in water C6H5NH2, (C2H5)2NH, C2H5NH2
Q24
short answer
3 marks
Calculate the cell voltage of the voltaic cell which is set up by joining the following half-cells at 25C: Al/Al3+ (0·001 M) and Ni/Ni2+ (0·001 M)
Q25
short answer
2 marks
Can sodium methoxide and t-butyl bromide be used for the preparation of t-butyl methyl ether. Give suitable reason. Justify your answer by suggesting the appropriate starting material if required for the preparation of t-butyl methyl ether.
Q26
short answer
1 mark
Give the IUPAC name of above mentioned ether.
Q26
short answer
3 marks
Give explanation for each of the following observations : (a) With the same d-orbital configuration (d4), Mn3+ ion is an oxidising agent whereas Cr2+ ion is a reducing agent. (b) Actinoid contraction is greater from element to element than that among lanthanoids. (c) Transition metals form large number of interstitial compounds with H, B, C and N.
Q27
short answer
3 marks
An aqueous solution of NaOH was made and its molar mass from the measurement of osmotic pressure at 27C was found to be 25 g mol–1. Calculate the percentage dissociation of NaOH in this solution. [Atomic mass : Na = 23 u, O = 16 u, H = 1 u]
Q28
short answer
3 marks
A compound ‘A’ with molecular formula C4H8O gives positive 2,4-DNP test. It gives yellow precipitate of compound ‘B’ on treatment with sodium hypoiodite. Compound ‘A’ does not react with Tollen’s or Fehling’s reagent; on drastic oxidation with KMnO4, it forms a carboxylic acid ‘C’. Elucidate the structures of ‘A’, ‘B’ and ‘C’. Also give their IUPAC names.
Q29
short answer
3 marks
Account for the following: (i) Allyl chloride is hydrolysed more readily than n-propyl chloride. (ii) Isocyanides are formed when alkyl halides are treated with silver cyanide. (iii) Methyl chloride reacts faster with – OH ion in SN2 reaction than t-butyl chloride.
Q30
short answer
3 marks
(i) CH3CH = CH2 HBr Peroxide ⎯⎯⎯⎯⎯⎯→ ‘A’ aq. KOH ⎯⎯⎯⎯⎯⎯→ ‘B’
Q31
short answer
3 marks
(ii) CH3CH2CHCH3 alc. KOH ⎯⎯⎯⎯⎯⎯→ ‘A’ HBr ⎯⎯⎯→ ‘B’ | Cl
Q32
short answer
3 marks
(iii) ‘A’ Mg ⎯⎯→ CH3CH2MgCl HO2 H ⎯⎯⎯⎯→+ ‘B’ (Main product)
Reading Passage
Ribose and 2-deoxyribose have an important role in biology. Among the most important derivatives are those with phosphate groups attached at the 5 position. Mono-, di- and tri-phosphate forms are important, as well as 3-5 cyclic monophosphates. Purines and pyrimidines form an important class of compounds with ribose and deoxyribose. When these purine and pyrimidine derivatives are coupled to a ribose sugar, they are called nucleosides.
Q36
short answer
2 marks
What products would be formed when DNA is hydrolysed ? How is DNA different from RNA with reference to a structure ?
Q37
short answer
1 mark
Differentiate between nucleotide and nucleoside.
Q38
short answer
1 mark
Mention two important functions of nucleic acid.
Q39
short answer
1 mark
Name the linkage which joins two nucleotides. Name the base that is found in nucleotide of RNA but not in DNA.
Reading Passage
According to the generally accepted definition of the ideal solution there are equal interaction forces acting between molecules belonging to the same or different species. (This is equivalent to the statement that the activity of the components equals the concentration.) Strictly speaking, this condition is fulfilled only in exceptional cases for mixtures (optical isomers, isotopic mixtures of an element, hydrocarbon mixtures). It is still usual to talk about ideal solutions as limiting cases in reality since very dilute solutions behave ideally with respect to the solvent. This view is further supported by the fact that Raoult’s law empirically found for describing the behaviour of the solvent in dilute solutions can be deduced thermodynamically via the assumption of ideal behaviour of the solvent.
Q40
short answer
2 marks
Give one example of miscible liquid pair which shows negative deviation from Raoult’s law. What is the reason for such deviation ?
Q41
short answer
1 mark
State Raoult’s law for a solution containing volatile components.
Q42
short answer
1 mark
Raoult’s law is a special case of Henry’s law. Comment.
Q43
short answer
1 mark
Write two characteristics of an ideal solution.
Q44
short answer
3 marks
The initial concentration of N2O5 in the first order reaction : N2O5(g) → 2NO2(g) + 1/2 O2(g) was 1·2 x 10–2 mol L–1. The concentration of N2O5 after 60 minutes was 0·2 x 10–2 mol L–1. Calculate the rate constant of the reaction at 318 K.
Q45
short answer
1 mark
We cannot determine the order of a reaction by taking into consideration the balanced chemical equation.
Q46
short answer
1 mark
A bimolecular reaction may become kinetically of first order under a specified condition.
Q47
short answer
3 marks
The rate of the chemical reaction doubles for an increase of 10 K in absolute temperature from 298 K. Calculate activation energy (Ea).
Q48
short answer
2 marks
For a reaction: 2H2O2 --(I)--> 2H2O + O2, the proposed mechanism is as given below: (I) H2O2 + I- -> H2O + IO- (slow); (II) H2O2 + IO- -> H2O + I- + O2 (fast). (1) Write rate law for the reaction. (2) Write the overall order and molecularity of the reaction.
Q49
short answer
2 marks
(ii) Account for the following : (I) We cannot determine the order of a reaction by taking into consideration the balanced chemical equation. (II) A bimolecular reaction may become kinetically of first order under a specified condition.
Q50
short answer
3 marks
(i) The rate of the chemical reaction doubles for an increase of 10 K in absolute temperature from 298 K. Calculate activation energy (Ea). [2·303 R = 19·15 JK–1 mol–1, log 2 = 0·3]
Q51
short answer
3 marks
(i) Complete the following reactions by writing the structure of the main products : (I) (II) (CH3)2Cd + 2CH3COCl → (III)
Q52
short answer
2 marks
(ii) Give simple chemical test to distinguish between the following pairs of compounds : (I) Ethyl benzoate and benzoic acid (II) Propanal and propanone
Q53
short answer
3 marks
(i) Complete each synthesis by giving missing starting material, reagent or products : (I) (II) (III)
Q54
short answer
2 marks
(ii) Carry out the following conversions : (I) Benzaldehyde to Benzophenone (II) Benzaldehyde to 3-phenyl propanol
Q55
short answer
3 marks
(i) Give reasons : (I) [Ni(CO)4] is diamagnetic whereas [NiCl4] 2– is paramagnetic. [Atomic number : Ni = 28] (II) CO is a stronger complexing agent than NH3. (III) The trans isomer of complex [Co(en)2Cl2]+ is optically inactive.
Q56
short answer
2 marks
(ii) Using Crystal Field theory, write the number of unpaired electrons in octahedral complexes of Fe3+ in the presence of : (I) Strong field ligand (II) Weak field ligand [Atomic number : Fe = 26]
Q57
short answer
3 marks
(i) Name the type of isomerism exhibited by the following compounds. Also draw their corresponding isomers. (I) [Co(NH3)6] [Cr(CN)6] (II) [Co(en)3] 3+ (III) [Co(NH3)3(NO2)3]
Q58
short answer
2 marks
(ii) Differentiate between weak field and strong field ligands. How does the strength of the ligand influence the spin of the complex ?