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JEE Main 2023 (11 Apr, Shift 1)

59 questions from this JEE Main 2023 paper. Log in to view the correct answer and explanation for each question.

Q1 MATHS Unit 1: Sets Relations and Functions
An organization awarded 48 medals in event $A$, 25 in event $B$ and 18 in event $C$. If these medals went to total 60 men and only five men got medals in all the three events, then how many received medals in exactly two of three events?
↻ Repeated question — also appeared in 2023 (1 set)
  • A. 15
  • B. 9
  • C. 10
  • D. 21

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Q2 MATHS Unit 12: Vector Algebra
Let $(\alpha, \beta, \gamma)$ be the image of the point $P(2, 3, 5)$ in the plane $2x + y - 3z = 6$. Then $\alpha + \beta + \gamma$ is equal to
  • A. 12
  • B. 10
  • C. 9
  • D. 5

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Q3 MATHS Unit 10: Co-ordinate Geometry
Consider ellipses $E_k: kx^2 + k^2 y^2 = 1$, $k=1,2,\ldots,20$. Let $C_k$ be the circle which touches the four chords joining the end points (one on minor axis and another on major axis) of the ellipse $E_k$. If $r_k$ is the radius of the circle $C_k$, then the value of $\sum_{k=1}^{20} \frac{1}{r_k^2}$ is
↻ Repeated question — also appeared in 2023 (1 set)
  • A. 2870
  • B. 3080
  • C. 3210
  • D. 3320

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Q4 MATHS Unit 4: Permutations and Combinations
The number of triplets $(x,y,z)$, where $x,y,z$ are distinct non negative integers satisfying $x+y+z=15$, is
↻ Repeated question — also appeared in 2023 (1 set)
  • A. 136
  • B. 114
  • C. 92
  • D. 80

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Q5 CHEMISTRY Unit 14: Some Basic Principles of Organic Chemistry
The number of integral solutions $x$ of $\log_{\left(x+7\right)/2}\!\left(\frac{(x-7)^2}{2x-3}\right) \ge 0$ is
↻ Repeated question — also appeared in 2023 (1 set)
  • A. 8
  • B. 7
  • C. 6
  • D. 5

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Q6 MATHS Unit 3: Matrices and Determinants
Let $A$ be a $2\times 2$ matrix with real entries such that $A^\prime = \alpha A + I$, where $\alpha \in \mathbb{R} - \{-1,1\}$. If $\det(A^2-A)=4$, then the sum of all possible values of $\alpha$ is equal to
↻ Repeated question — also appeared in 2023 (1 set)
  • A. $\frac{5}{2}$
  • B. $\frac{3}{2}$
  • C. 2

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Q7 MATHS Unit 7: Limit Continuity and Differentiability
Let $f(x) = [x^2-x] + [-x+[x]]$, where $x\in\mathbb{R}$ and $[t]$ denotes the greatest integer less than or equal to $t$. Then, $f$ is
↻ Repeated question — also appeared in 2023 (1 set)
  • A. not continuous at $x=0$ and $x=1$
  • B. continuous at $x=0$ and $x=1$
  • C. continuous at $x=0$, but not continuous at $x=1$
  • D. continuous at $x=1$, but not continuous at $x=0$

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Q8 MATHS Unit 10: Co-ordinate Geometry
If equation of the plane that contains the point $(-2,3,5)$ and is perpendicular to each of the planes $2x+4y+5z=8$ and $3x-2y+3z=5$ is $\alpha x+\beta y+\gamma z+97=0$ then $\alpha+\beta+\gamma$ =
↻ Repeated question — also appeared in 2023 (1 set)
  • A. 15
  • B. 16
  • C. 17
  • D. 18

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Q9 MATHS Unit 8: Integral Calculus
Area of the region $\{(x,y): x^2+(y-2)^2\le 4,\ x^2\ge 2y\}$ is
↻ Repeated question — also appeared in 2023 (1 set)
  • A. $\pi-\frac{8}{3}$
  • B. $2\pi-\frac{16}{3}$
  • C. $\pi+\frac{8}{3}$
  • D. $2\pi+\frac{16}{3}$

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Q10 MATHS Unit 7: Limit Continuity and Differentiability
Let $f:[2,4]\to \mathbb{R}$ be a differentiable function such that $$(x\log_e x)\,f'(x)+(\log_e x)f(x)+f(x)\ge 1,\ x\in[2,4]$$ with $f(2)=\frac{1}{2}$ and $f(4)=\frac{1}{4}$. Consider the following two statements : (A) : $f(x)\le 1$, for all $x\in[2,4]$ (B) : $f(x)\ge \frac{1}{8}$, for all $x\in[2,4]$ Then,
↻ Repeated question — also appeared in 2023 (1 set)
  • A. Only statement (A) is true
  • B. Only statement (B) is true
  • C. Both statements (A) and (B) are true
  • D. Neither statement (A) nor statement (B) is true

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Q11 MATHS Unit 12: Vector Algebra
Let $\vec{a}$ be a non-zero vector parallel to the line of intersection of the two planes described by $\hat{i}+\hat{j},\ \hat{i}+\hat{k}$ and $\hat{i}-\hat{j},\ \hat{j}-\hat{k}$. If $\theta$ is the angle between the vector $\vec{a}$ and the vector $\vec{b}=2\hat{i}-2\hat{j}+\hat{k}$, and $\vec{a}\cdot\vec{b}=6$, then the ordered pair $(\theta, |\vec{a}\times\vec{b}|)$ is equal to
↻ Repeated question — also appeared in 2023 (1 set)
  • A. $(\pi/4,\ 3\sqrt{6})$
  • B. $(\pi/3,\ 6)$
  • C. $(\pi/3,\ 3\sqrt{6})$
  • D. $(\pi/4,\ 6)$

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Q12 MATHS Unit 12: Vector Algebra
For any vector $\vec{a}=a_1\hat{i}+a_2\hat{j}+a_3\hat{k}$, with $10|a_i|<1$, $i=1,2,3$, consider the following statements : (A) : $\max\{|a_1|,|a_2|,|a_3|\}\le |\vec{a}|$ (B) : $|\vec{a}|\le 3\max\{|a_1|,|a_2|,|a_3|\}$
↻ Repeated question — also appeared in 2023 (1 set)
  • A. Only (A) is true
  • B. Only (B) is true
  • C. Both (A) and (B) are true
  • D. Neither (A) nor (B) is true

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Q13 MATHS Unit 6: Sequence and Series
Let $x_1,x_2,\ldots,x_{100}$ be in an arithmetic progression, with $x_1=2$ and their mean equal to $200$. If $y_i=i(x_i-i)$, $1\le i\le 100$, then the mean of $y_1,y_2,\ldots,y_{100}$ is
↻ Repeated question — also appeared in 2023 (1 set)
  • A. 10051.50
  • B. 10049.50
  • C. 10101.50
  • D. 10100

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Q14 MATHS Unit 2: Complex Numbers and Quadratic Equations
Let $w_1$ be the point obtained by the rotation of $z_1=5+4i$ about the origin through a right angle in the anticlockwise direction, and $w_2$ be the point obtained by the rotation of $z_2=3-5i$ about the origin through a right angle in the clockwise direction. Then the principal argument of $w_1-w_2$ is equal to
↻ Repeated question — also appeared in 2023 (1 set)
  • A. $\pi-\tan^{-1}\!\left(\frac{33}{5}\right)$
  • B. $-\pi+\tan^{-1}\!\left(\frac{33}{5}\right)$
  • C. $\pi-\tan^{-1}\!\left(\frac{8}{9}\right)$
  • D. $-\pi+\tan^{-1}\!\left(\frac{8}{9}\right)$

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Q15 MATHS Unit 8: Integral Calculus
The value of the integral $$\int_{-\log_e 2}^{\log_e 2}\log_e\!\left(e^x+\sqrt{1+e^{2x}}\right)dx$$ is equal to
↻ Repeated question — also appeared in 2023 (1 set)
  • A. $\log_e\!\left(\dfrac{(2+\sqrt5)^2}{\sqrt{1+\sqrt5}}\right)+\dfrac{\sqrt5}{2}$
  • B. $\log_e\!\left(\dfrac{\sqrt2(2+\sqrt5)^2}{\sqrt{1+\sqrt5}}\right)-\dfrac{\sqrt5}{2}$
  • C. $\log_e\!\left(\dfrac{2(2+\sqrt5)}{\sqrt{1+\sqrt5}}\right)-\dfrac{\sqrt5}{2}$
  • D. $\log_e\!\left(\dfrac{\sqrt2(3-\sqrt5)^2}{\sqrt{1+\sqrt5}}\right)+\dfrac{\sqrt5}{2}$

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Q16 MATHS Unit 14: Trigonometry
The number of elements in the set $$S=\{\theta\in[0,2\pi]:3\cos^4\theta-5\cos^2\theta-2\sin^6\theta+2=0\}$$ is
↻ Repeated question — also appeared in 2023 (1 set)
  • A. 8
  • B. 9
  • C. 10
  • D. 12

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Q17 MATHS Unit 13: Statistics and Probability
Let $S = \{M = [a_{ij}],\ a_{ij} \in \{0,1,2\},\ 1 \le i,j \le 2\}$ be a sample space and $A = \{M \in S : M \text{ is invertible}\}$ be an event. Then $P(A)$ is equal to
↻ Repeated question — also appeared in 2023 (1 set)
  • A. $\frac{47}{81}$
  • B. $\frac{16}{27}$
  • C. $\frac{49}{81}$
  • D. $\frac{50}{81}$

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Q18 MATHS Unit 13: Statistics and Probability
Let sets $A$ and $B$ have $5$ elements each. Let the mean of the elements in sets $A$ and $B$ be $5$ and $8$ respectively and the variance of the elements in sets $A$ and $B$ be $12$ and $20$ respectively. A new set $C$ of $10$ elements is formed by subtracting $3$ from each element of $A$ and adding $2$ to each element of $B$. Then the sum of the mean and variance of the elements of $C$ is _____________.
↻ Repeated question — also appeared in 2023 (1 set)
  • A. 38
  • B. 32
  • C. 36
  • D. 40

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Q19 MATHS Unit 10: Co-ordinate Geometry
Let $R$ be a rectangle given by the lines $x = 0$, $x = 2$, $y = 0$ and $y = 5$. Let $A(a,0)$ and $B(0,b)$, $a \in [0,2]$ and $b \in [0,5]$, be such that the line segment $AB$ divides the area of the rectangle $R$ in the ratio $4:1$. Then the mid-point of $AB$ lies on a
↻ Repeated question — also appeared in 2023 (1 set)
  • A. straight line
  • B. parabola
  • C. hyperbola
  • D. circle

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Q31 PHYSICS Unit 16: Optics
A transmitting antenna is kept on the surface of the earth. The minimum height of receiving antenna required to receive the signal in line of sight at $4\,\text{km}$ distance from it is $x \times 10^{-2}\,\text{m}$. The value of $x$ is ________. (Let, radius of earth $R = 6400\,\text{km}$)
  • A. 1.25
  • B. 12.5
  • C. 125
  • D. 1250

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Q32 PHYSICS Unit 19: Electronic Devices
The logic performed by the circuit shown in figure is equivalent to:
Question 32 image
↻ Repeated question — also appeared in 2023 (1 set)
  • A. OR
  • B. NAND
  • C. AND
  • D. NOR

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Q33 PHYSICS Unit 18: Atoms and Nuclei
Two radioactive elements A and B initially have same number of atoms. The half life of A is same as the average life of B. If $\lambda_A$ and $\lambda_B$ are decay constants of A and B respectively, then choose the correct relation from the given options.
↻ Repeated question — also appeared in 2023 (1 set)
  • A. $\lambda_A \ln 2 = \lambda_B$
  • B. $\lambda_A = \lambda_B \ln 2$
  • C. $\lambda_A = \lambda_B$
  • D. $\lambda_A = 2\lambda_B$

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Q34 PHYSICS Unit 17: Dual Nature of Matter and Radiation
A metallic surface is illuminated with radiation of wavelength $\lambda$, the stopping potential is $V_0$. If the same surface is illuminated with radiation of wavelength $2\lambda$, the stopping potential becomes $\frac{V_0}{4}$. The threshold wavelength for this metallic surface will be
↻ Repeated question — also appeared in 2023 (1 set)
  • A. $4\lambda$
  • B. $\frac{3}{2}\lambda$
  • C. $3\lambda$
  • D. $\frac{\lambda}{4}$

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Q35 PHYSICS Unit 16: Optics
The critical angle for a denser-rarer interface is $45^\circ$. The speed of light in rarer medium is $3 \times 10^8$ m/s. The speed of light in the denser medium is:
↻ Repeated question — also appeared in 2023 (1 set)
  • A. $2.12 \times 10^8$ m/s
  • B. $3.12 \times 10^7$ m/s
  • C. $5 \times 10^7$ m/s
  • D. $\sqrt{2} \times 10^8$ m/s

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Q36 PHYSICS Unit 14: Electromagnetic Induction and Alternating Currents
As per the given graph, choose the correct representation for curve A and curve B. Where $X_C$ = reactance of pure capacitive circuit connected with A.C. source $X_L$ = reactance of pure inductive circuit connected with A.C. source $R$ = impedance of pure resistive circuit connected with A.C. source $Z$ = impedance of the LCR series circuit
Question 36 image
↻ Repeated question — also appeared in 2023 (1 set)
  • A. $A = X_C,\ B = X_L$
  • B. $A = X_L,\ B = Z$
  • C. $A = X_C,\ B = R$
  • D. $A = X_L,\ B = R$

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Q37 PHYSICS Unit 15: Electromagnetic Waves
The electric field in an electromagnetic wave is given as $\vec{E} = 20\sin\omega\left(t - \dfrac{x}{c}\right)\hat{j}$ N$^{-1}$ C where $\omega$ and $c$ are angular frequency and velocity of electromagnetic wave respectively. The energy contained in a volume of $5 \times 10^{-4}$ m$^3$ will be (Given $\varepsilon_0 = 8.85 \times 10^{-12}$ C$^2$/Nm$^2$)
↻ Repeated question — also appeared in 2023 (1 set)
  • A. $8.85 \times 10^{-13}$ J
  • B. $88.5 \times 10^{-13}$ J
  • C. $28.5 \times 10^{-13}$ J
  • D. $17.7 \times 10^{-13}$ J

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Q38 PHYSICS Unit 13: Magnetic Effects of Current and Magnetism
The free space inside a current carrying toroid is filled with a material of susceptibility $2 \times 10^{-2}$. The percentage increase in the value of magnetic field inside the toroid will be
↻ Repeated question — also appeared in 2023 (1 set)
  • A. 2%
  • B. 0.2%
  • C. 1%
  • D. 0.1%

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Q39 PHYSICS Unit 12: Current Electricity
The current sensitivity of moving coil galvanometer is increased by 25%. This increase is achieved only by changing in the number of turns of coils and area of cross section of the wire while keeping the resistance of galvanometer coil constant. The percentage change in the voltage sensitivity will be:
↻ Repeated question — also appeared in 2023 (1 set)
  • A. +25%
  • B. -25%
  • C. Zero
  • D. -50%

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Q40 PHYSICS Unit 4: Work Energy and Power
Two identical heater filaments are connected first in parallel and then in series. At the same applied voltage, the ratio of heat produced in same time for parallel to series will be:
  • A. 1 : 4
  • B. 4 : 1
  • C. 1 : 2
  • D. 2 : 1

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Q41 PHYSICS Unit 12: Current Electricity
A parallel plate capacitor of capacitance $2$ F is charged to a potential $V$. The energy stored in the capacitor is $E_1$. The capacitor is now connected to another uncharged identical capacitor in parallel combination. The energy stored in the combination is $E_2$. The ratio $E_2/E_1$ is:
  • A. 1 : 2
  • B. 2 : 1
  • C. 2 : 3
  • D. 1 : 4

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Q42 PHYSICS Unit 4: Work Energy and Power
The variation of kinetic energy (KE) of a particle executing simple harmonic motion with the displacement $(x)$ starting from mean position to extreme position $(A)$ is given by
Question 42 image
  • A. Graph rising linearly from $0$ to maximum at $A$
  • B. Graph constant with $x$
  • C. Graph rising nonlinearly from $0$ to maximum at $A$
  • D. Graph falling from maximum at $x=0$ to $0$ at $A$

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Q43 PHYSICS Unit 9: Kinetic Theory of Gases
Three vessels of equal volume contain gases at the same temperature and pressure. The first vessel contains neon (monoatomic), the second contains chlorine (diatomic) and third contains uranium hexafluoride (polyatomic). Arrange these on the basis of their root mean square speed ($v_{\text{rms}}$) and choose the correct answer from the options given below:
↻ Repeated question — also appeared in 2023 (1 set)
  • A. $v_{\text{rms}}$(mono) > $v_{\text{rms}}$(dia) > $v_{\text{rms}}$(poly)
  • B. $v_{\text{rms}}$(mono) < $v_{\text{rms}}$(dia) < $v_{\text{rms}}$(poly)
  • C. $v_{\text{rms}}$(mono) = $v_{\text{rms}}$(dia) = $v_{\text{rms}}$(poly)
  • D. $v_{\text{rms}}$(dia) < $v_{\text{rms}}$(poly) < $v_{\text{rms}}$(mono)

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Q44 PHYSICS Unit 8: Thermodynamics
1 kg of water at 100$^\circ$C is converted into steam at 100$^\circ$C by boiling at atmospheric pressure. The volume of water changes from $1.00 \times 10^{-3}\ \text{m}^3$ as a liquid to $1.671\ \text{m}^3$ as steam. The change in internal energy of the system during the process will be (Given latent heat of vaporisation = 2257 kJ/kg, Atmospheric pressure = $1 \times 10^5\ \text{Pa}$)
↻ Repeated question — also appeared in 2023 (1 set)
  • A. $-2090\ \text{kJ}$
  • B. $+2090\ \text{kJ}$
  • C. $-2426\ \text{kJ}$
  • D. $+2476\ \text{kJ}$

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Q45 MATHS Unit 14: Trigonometry
On a temperature scale 'X', the boiling point of water is 65$^\circ$X and the freezing point is $-15^\circ$X. Assume that the X scale is linear. The equivalent temperature corresponding to $-95^\circ$X on the Fahrenheit scale would be:
  • A. $-48^\circ$F
  • B. $-63^\circ$F
  • C. $-112^\circ$F
  • D. $-148^\circ$F

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Q46 PHYSICS Unit 6: Gravitation
The radii of two planets 'A' and 'B' are 'R' and '4R' and their densities are $\rho$ and $\rho/3$ respectively. The ratio of acceleration due to gravity at their surfaces $(g_A : g_B)$ will be:
↻ Repeated question — also appeared in 2023 (1 set)
  • A. 3 : 16
  • B. 4 : 3
  • C. 3 : 4
  • D. 1 : 16

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Q47 PHYSICS Unit 2: Kinematics
From the $v$ - $t$ graph shown, the ratio of distance to displacement in 25 s of motion is:
Question 47 image
↻ Repeated question — also appeared in 2023 (1 set)
  • A. 1
  • B. $\frac{1}{2}$
  • C. $\frac{5}{3}$
  • D. $\frac{3}{5}$

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Q48 PHYSICS Unit 5: Rotational Motion
A coin placed on a rotating table just slips when it is placed at a distance of 1 cm from the center. If the angular velocity of the table is halved, it will just slip when placed at a distance of ____ from the centre :
  • A. 1 cm
  • B. 2 cm
  • C. 4 cm
  • D. 8 cm

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Q49 PHYSICS Unit 4: Work Energy and Power
An average force of 125 N is applied on a machine gun firing bullets each of mass 10 g at the speed of 250 m/s to keep it in position. The number of bullets fired per second by the machine gun is:
  • A. 5
  • B. 100
  • C. 50
  • D. 25

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Q50 PHYSICS Unit 1: Units and Measurements
Given below are two statements : Statements I : Astronomical unit (Au), Parsec (Pc) and Light year (ly) are units for measuring astronomical distances. Statements II : Au < Parsec (Pc) < ly In the light of the above statements, choose the most appropriate answer from the options given below:
  • A. Both Statements I and Statements II are correct
  • B. Both Statements I and Statements II are incorrect
  • C. Statements I is correct but Statements II is incorrect
  • D. Statements I is incorrect but Statements II is correct

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Q61 CHEMISTRY Unit 12: Coordination Compounds
Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R: Assertion A: In the photoelectric effect, the electrons are ejected from the metal surface as soon as the beam of light of frequency greater than threshold frequency strikes the surface. Reason R: When the photon of any energy strikes an electron in the atom, transfer of energy from the photon to the electron takes place. In the light of the above statements, choose the most appropriate answer from the options given below:
↻ Repeated question — also appeared in 2023 (1 set)
  • A. Both A and R are correct and R is the correct explanation of A
  • B. Both A and R are correct but R is NOT the correct explanation of A
  • C. A is correct but R is not correct
  • D. A is not correct but R is correct

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Q62 CHEMISTRY Unit 3: Chemical Bonding and Molecular Structure
Match List-I with List-II: List-I Species A. $\mathrm{H_3O^+}$ B. Acetylide anion C. $\mathrm{NH_4^+}$ D. $\mathrm{ClO_2^-}$ List-II Geometry/Shape I. Tetrahedral II. Linear III. Pyramidal IV. Bent Choose the correct answer from the options given below:
↻ Repeated question — also appeared in 2023 (1 set)
  • A. A-III, B-II, C-I, D-IV
  • B. A-III, B-I, C-II, D-IV
  • C. A-III, B-IV, C-I, D-II
  • D. A-III, B-IV, C-II, D-I

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Q63 CHEMISTRY Unit 6: Equilibrium
$25\ \mathrm{mL}$ of silver nitrate solution $(1\ \mathrm{M})$ is added dropwise to $25\ \mathrm{mL}$ potassium iodide $(1.05\ \mathrm{M})$ solution. The ion(s) present in very small quantity in the solution is/are
↻ Repeated question — also appeared in 2023 (1 set)
  • A. $\mathrm{I^-}$ only
  • B. $\mathrm{Ag^+}$ and $\mathrm{I^-}$ both
  • C. $\mathrm{K^+}$ only
  • D. $\mathrm{NO_3^-}$ only

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Q64 CHEMISTRY Unit 9: Classification of Elements and Periodicity in Properties
For elements B, C, N, Li, Be, O and F, the correct order of first ionization enthalpy is
↻ Repeated question — also appeared in 2023 (1 set)
  • A. $\mathrm{Li < Be < B < C < N < O < F}$
  • B. $\mathrm{Li < B < Be < C < O < N < F}$
  • C. $\mathrm{B > Li > Be > C > N > O > F}$
  • D. $\mathrm{Li < Be < B < C < O < N < F}$

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Q65 CHEMISTRY Unit 11: d- and f-Block Elements
In the extraction process of copper, the product obtained after carrying out the reactions (i) $2\mathrm{Cu_2S} + 3\mathrm{O_2} \rightarrow 2\mathrm{Cu_2O} + 2\mathrm{SO_2}$ (ii) $2\mathrm{Cu_2O} + \mathrm{Cu_2S} \rightarrow 6\mathrm{Cu} + \mathrm{SO_2}$ is called
↻ Repeated question — also appeared in 2023 (1 set)
  • A. Copper matte
  • B. Copper scrap
  • C. Blister copper
  • D. Reduced copper

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Q66 CHEMISTRY Unit 7: Redox Reactions and Electrochemistry
Given below are two statements: Statement-I: Methane and steam passed over a heated Ni catalyst produces hydrogen gas. Statement-II: Sodium nitrite reacts with $\mathrm{NH_4Cl}$ to give $\mathrm{H_2O}$, $\mathrm{N_2}$ and $\mathrm{NaCl}$. In the light of the above statements, choose the most appropriate answer from the options given below:
  • A. Both the statements I and II are correct
  • B. Both the statements I and II are incorrect
  • C. Statement I is correct but Statement II is incorrect
  • D. Statement I is incorrect but Statement II is correct

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Q67 CHEMISTRY Unit 11: d- and f-Block Elements
Match List-I with List-II: List-I A. K B. KCl C. KOH D. Li List-II I. Thermonuclear reactions II. Fertilizer III. Sodium potassium pump IV. Absorbent of $\mathrm{CO_2}$ Choose the correct answer from the options given below:
  • A. A-IV, B-I, C-III, D-II
  • B. A-IV, B-III, C-I, D-II
  • C. A-III, B-IV, C-II, D-I
  • D. A-III, B-II, C-IV, D-I

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Q68 CHEMISTRY Unit 10: p-Block Elements
For compound having the formula $\mathrm{GaAlCl_4}$, the correct option from the following is
  • A. Oxidation state of Ga in the salt $\mathrm{GaAlCl_4}$ is $+3$.
  • B. Ga is coordinated with Cl in $\mathrm{GaAlCl_4}$
  • C. Ga is more electronegative than Al and is present as a cationic part of the salt $\mathrm{GaAlCl_4}$
  • D. Cl forms bond with both Al and Ga in $\mathrm{GaAlCl_4}$

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Q69 CHEMISTRY Unit 12: Coordination Compounds
Which of the following complex has a possibility to exist as meridional isomer?
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  • A. [Co(NH$_3$)$_3$(NO$_2$)$_3$]
  • B. [Co(en)$_3$]
  • C. [Co(en)$_2$Cl$_2$]
  • D. [Pt(NH$_3$)$_2$Cl$_2$]

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Q70 CHEMISTRY Unit 13: Purification and Characterisation of Organic Compounds
The set which does not have ambidentate ligand(s) is
  • A. $\mathrm{EDTA}^{4-},\ \mathrm{NCS}^-,\ \mathrm{C_2O_4^{2-}}$
  • B. $\mathrm{NO_2^-},\ \mathrm{C_2O_4^{2-}},\ \mathrm{EDTA}^{4-}$
  • C. $\mathrm{C_2O_4^{2-}},\ \text{ethylene diamine},\ \mathrm{H_2O}$
  • D. $\mathrm{C_2O_4^{2-}},\ \mathrm{NO_2^-},\ \mathrm{NCS}^-$

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Q71 CHEMISTRY Unit 20: Principles Related to Practical Chemistry
Given below are two statements: Statement I: If BOD is 4 ppm and dissolved oxygen is 8 ppm, then it is a good quality water. Statement II: If the concentration of zinc and nitrate salts are 5 ppm each, then it can be a good quality water. In the light of the above statements, choose the most appropriate answer from the options given below:
↻ Repeated question — also appeared in 2023 (1 set)
  • A. Both the statements I and II are correct
  • B. Both the statements I and II are incorrect
  • C. Statement I is correct but Statement II is incorrect
  • D. Statement I is incorrect but Statement II is correct

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Q72 CHEMISTRY Unit 13: Purification and Characterisation of Organic Compounds
Thin layer chromatography of a mixture shows the following observation: The correct order of elution in the silica gel column chromatography is
Question 72 image
↻ Repeated question — also appeared in 2023 (1 set)
  • A. B, C, A
  • B. A, C, B
  • C. C, A, B
  • D. B, A, C

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Q73 CHEMISTRY Unit 16: Organic Compounds Containing Halogens
Arrange the following compounds in increasing order of rate of aromatic electrophilic substitution reaction
Question 73 image
  • A. c, a, b, d
  • B. b, c, a, d
  • C. d, b, c, a
  • D. d, b, a, c

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Q74 CHEMISTRY Unit 14: Some Basic Principles of Organic Chemistry
Where $\mathrm{Nu} =$ nucleophile, find out the correct statement from the options given below for the above 2 reactions.
Question 74 image
  • A. Reaction (I) is of 1st order and reaction (II) is of 2nd order
  • B. Reactions (I) and (II) both are of 1st order
  • C. Reactions (I) and (II) both are of 2nd order
  • D. Reaction (I) is of 2nd order and reaction (II) is of 1st order

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Q75 CHEMISTRY Unit 17: Organic Compounds Containing Oxygen
$A$ and $B$ in the above reactions are:
Question 75 image
  • A. $A = \mathrm{CO_2H}$-terminated keto acid; $B = \mathrm{CO_2H}$-terminated alkane
  • B. A dicarboxylic acid derivative and B a hydrazone-containing product
  • C. $A$ is a keto acid and $B$ is the corresponding open-chain acid after Wolff-Kishner reduction
  • D. $A$ is a keto acid and $B$ is the corresponding hydrocarbon with one carbonyl reduced to $\mathrm{CH_2}$

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Q76 CHEMISTRY Unit 12: Coordination Compounds
The complex that dissolves in water is
↻ Repeated question — also appeared in 2023 (1 set)
  • A. $[\mathrm{Fe_3(OH)_2(OAc)_6}]\,\mathrm{Cl}$
  • B. $\mathrm{K_3[Co(NO_2)_6]}$
  • C. $\mathrm{Fe_4[Fe(CN)_6]_3}$
  • D. $\mathrm{(NH_4)_3[As(Mo_3O_{10})_4]}$

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Q77 CHEMISTRY Unit 18: Organic Compounds Containing Nitrogen
o-Phenylenediamine reacts with $\mathrm{HNO_2}$ to give 'X'. 'X' is major product.
  • A. Benzotriazole (benzene ring fused with a five-membered ring containing three nitrogens) Choice A image
  • B. Benzotriazole tautomer with one $\mathrm{N-H}$ group Choice B image
  • C. o-Diazoniobenzene-type intermediate with two diazonium groups Choice C image
  • D. Indazole-like fused bicyclic compound with $\mathrm{NH}$ Choice D image

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Q78 CHEMISTRY Unit 15: Hydrocarbons
The polymer $X$ consists of linear molecules and is closely packed. It is prepared in the presence of triethylaluminium and titanium tetrachloride under low pressure. The polymer $X$ is-
↻ Repeated question — also appeared in 2023 (1 set)
  • A. Polytetrafluoroethane
  • B. Polyacrylonitrile
  • C. High density polythene
  • D. Low density polythene

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Q79 CHEMISTRY Unit 17: Organic Compounds Containing Oxygen
L-isomer of tetrose $X$ ($\mathrm{C_4H_8O_4}$) gives positive Schiff's test and has two chiral carbons. On acetylation, $X$ yields triacetate. $X$ also undergoes following reactions: $X' \xrightarrow[\mathrm{NaBH_4}]{} B'$ (chiral compound) $X'$ \xrightarrow{\mathrm{HNO_3}} A' $X$ is
  • A. L-erythrose Choice A image
  • B. L-threose Choice B image
  • C. D-erythrose Choice C image
  • D. D-threose Choice D image

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Q80 CHEMISTRY Unit 6: Equilibrium
When a solution of mixture having two inorganic salts was treated with freshly prepared ferrous sulphate in acidic medium, a dark brown ring was formed whereas on treatment with neutral $\mathrm{FeCl_3}$ it gave deep red colour which disappeared on boiling and a brown red ppt was formed. The mixture contains
  • A. $\mathrm{C_2O_4^{2-}}$ and $\mathrm{NO_3^-}$
  • B. $\mathrm{CH_3COO^-}$ and $\mathrm{NO_3^-}$
  • C. $\mathrm{SO_3^{2-}}$ and $\mathrm{CH_3COO^-}$
  • D. $\mathrm{SO_3^{2-}}$ and $\mathrm{C_2O_4^{2-}}$

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