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Q1
mcq
1 mark
In an electrochemical cell, the following reaction takes place : 2Cu+(aq) + Zn (s) → 2Cu (s) + Zn2+ (aq) Ecell = 1·28 V As the reaction progresses, what will happen to the overall voltage of the cell ?
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A.
Voltage will remain constant.
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B.
It will decrease as [Zn2+] increases.
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C.
It will increase as [Cu+] increases.
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D.
It will increase as [Zn2+] increases.
Q2
mcq
1 mark
Out of Ti3+, Cr3+ , Fe2+ and Ni2+ ions, the one which is the most stable ion in aqueous solution is : [Atomic number : Ti = 22, Cr = 24, Fe = 26, Ni = 28]
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A.
Ti3+
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B.
Cr3+
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C.
Fe2+
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D.
Ni2+
Q3
mcq
1 mark
Hoffmann Bromamide degradation reaction is given by :
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A.
R – NO2
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B.
R – NH2
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C.
R – CH2 – NH2
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D.
R – CO – NH2
Q4
mcq
1 mark
The value of Henry’s constant KH is :
-
A.
greater for gases with higher solubility
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B.
greater for gases with lower solubility
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C.
constant for all gases
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D.
not related to the solubility of gases
Q5
mcq
1 mark
In the Haworth structure of the following carbohydrate, various carbon atoms have been numbered. The anomeric carbon is numbered as :
Q6
mcq
1 mark
Out of the following statements, the correct statement is :
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A.
La is actually not an element of transition series.
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B.
Zr and Hf have almost identical atomic radii.
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C.
Lanthanoids are radioactive.
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D.
Ionic radius increases from La3+ to Lu3+.
Q7
mcq
1 mark
In the given reaction sequence, the structure of Y would be :
Q8
mcq
1 mark
Out of 2-Bromobutane, 1-Bromobutane, 2-Bromopropane and 1-Bromopropane, the molecule which is chiral in nature is :
-
A.
2-Bromobutane
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B.
1-Bromobutane
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C.
2-Bromopropane
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D.
1-Bromopropane
Q9
mcq
1 mark
Which of the following properties of transition metals enables them to behave as catalysts ?
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A.
High melting point
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B.
High ionisation enthalpy
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C.
Alloy formation
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D.
Variable oxidation states
Q10
mcq
1 mark
What amount of electric charge is required for the oxidation of 1 mole of FeO to Fe2O3 ?
Q11
mcq
Alkenes are formed by heating alcohols with conc. H2SO4. The first step in the reaction is :
-
A.
formation of carbocation
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B.
formation of ester
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C.
protonation of alcohol molecule
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D.
elimination of water
Q12
mcq
Polyhalogen compounds have wide application in industries and agriculture. DDT is also a very important polyhalogen compound. It is a :
-
A.
greenhouse gas
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B.
fertilizer
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C.
biodegradable insecticide
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D.
non-biodegradable insecticide
Q13
mcq
Assertion (A) : Acetanilide is less basic than aniline. Reason (R) : Acetylation of aniline results in decrease of electron density on nitrogen.
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A.
Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A).
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B.
Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of the Assertion (A).
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C.
Assertion (A) is true, but Reason (R) is false.
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D.
Assertion (A) is false, but Reason (R) is true.
Q14
mcq
Assertion (A) : Cuprous salts are diamagnetic. Reason (R) : Cuprous ion has completely filled 3d-orbitals.
-
A.
Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A).
-
B.
Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of the Assertion (A).
-
C.
Assertion (A) is true, but Reason (R) is false.
-
D.
Assertion (A) is false, but Reason (R) is true.
Q15
mcq
Assertion (A) : n-Butyl chloride has higher boiling point than n-Butyl bromide. Reason (R) : C – Cl bond is more polar than C – Br bond.
-
A.
Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A).
-
B.
Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of the Assertion (A).
-
C.
Assertion (A) is true, but Reason (R) is false.
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D.
Assertion (A) is false, but Reason (R) is true.
Q16
mcq
Assertion (A) : Electrolysis of aqueous NaCl gives H2 at cathode and Cl2 at anode. Reason (R) : Chlorine has higher oxidation potential than H2O.
-
A.
Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A).
-
B.
Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of the Assertion (A).
-
C.
Assertion (A) is true, but Reason (R) is false.
-
D.
Assertion (A) is false, but Reason (R) is true.
Q17
short answer
2 marks
What is meant by essential amino acids ? Why are amino acids amphoteric in nature ?
Q18
short answer
2 marks
Write the structures of the main products of the following reactions : (a) CH3-C-OH (b) 6CH3 – C – OH + 2Al
Q18
short answer
2 marks
Write the structures of the main products of the following reactions : (a) [Structural diagram not provided] (b) 6CH3 – C – OH + 2Al → [Structural diagram not provided]
Q19
short answer
2 marks
Name and define the cell which was used for providing electric power in the Apollo space programme. Also write its one advantage.
Q20
short answer
2 marks
PdCl2 . 2KCl does not give precipitate of AgCl with AgNO3 solution. Write the structural formula and IUPAC name of the complex.
Q21
short answer
2 marks
The reaction between A2(g) and B2(g) was carried out in a sealed isothermal container. The rate law for the reaction: Rate = k[A2][B2]. If 1 mole of A2(g) was added to the reaction vessel while keeping the temperature constant, predict the change in reaction rate and rate constant.
Q22
short answer
2 marks
A reactant 'A' decomposes. The concentration of 'A' was measured at specific intervals as shown in the table below: Time/hours [A]/M, 0 0.88, 1 0.44, 2 0.22, 3 0.11. Based on the data, predict the order of the reaction and write the expression for its rate law.
Q22
short answer
3 marks
Give explanation for each of the following observations : (a) With the same d-orbital configuration (d4), Mn3+ ion is an oxidising agent whereas Cr2+ ion is a reducing agent. (b) Actinoid contraction is greater from element to element than that among lanthanoids. (c) Transition metals form large number of interstitial compounds with H, B, C and N.
Q23
short answer
3 marks
An aromatic compound ‘A’ with molecular formula C8H8O gives positive 2,4-DNP test. It gives yellow precipitate of compound ‘B’ on treatment with sodium hypoiodite. Compound ‘A’ does not react with Tollen’s or Fehling’s reagent; on drastic oxidation with KMnO4 it forms a carboxylic acid ‘C’. Elucidate the structures of A, B and C. Also give their IUPAC names.
Q24
short answer
2 marks
Reactant ‘A’ underwent a decomposition reaction. The concentration of ‘A’ was measured periodically and recorded in the table given below: Time/Hours: 0, 1, 2, 3. [A]/M: 0.88, 0.44, 0.22, 0.11. Based on the above data, predict the order of the reaction and write the expression for the rate law.
Q24
short answer
3 marks
Arrange the following compounds as asked : (a) in decreasing order of pKb values: C2H5NH2, (C2H5)2NH, C6H5NHCH3, C6H5NH2 (b) increasing order of boiling point: C2H5OH, C2H5NH2, (CH3)2NH (c) increasing order of solubility in water: C6H5NH2, (C2H5)2NH, C2H5NH2
Q27
short answer
3 marks
An aqueous solution of NaOH was made and its molar mass from the measurement of osmotic pressure at 25°C was found to be 28 g mol–1. Calculate the percentage dissociation of NaOH in this solution. [Atomic mass : Na = 23.0 u, O = 16.0 u, H = 1.0 u]
Q28
short answer
3 marks
Account for the following : (i) Allyl chloride is hydrolysed more readily than n-propyl chloride. (ii) Isocyanides are formed when alkyl halides are treated with silver cyanide. (iii) In SN2 reaction, methyl chloride reacts more readily with -OH ion than t-butyl chloride.
Q28
short answer
3 marks
Calculate the cell voltage of the voltaic cell which is set up by joining the following half-cells at 25°C. Al/Al3+ (0.002 M) and Ni/Ni2+ (0.002 M) Given : E° Ni/Ni2+ = – 0.25 V, E° Al/Al3+ = – 1.66 V, log 5 = 0.6990
Q29
short answer
3 marks
Write the structural formulas of ‘A’ and ‘B’ to complete the following reactions : (i) CH3CH = CH2 + HBr -> ‘A’ --(KOH)--> ‘B’ (ii) CH3CH2CH(Cl)CH3 --(alc. KOH)--> ‘A’ --(HBr)--> ‘B’ (iii) ‘A’ --(Mg)--> CH3CH2MgCl --(H2O)--> ‘B’ (major product)
Q30
short answer
2 marks
Can sodium propoxide and tertiary-butyl chloride be used to prepare tertiary-butyl propyl ether? Give appropriate explanation. Suggest the suitable starting materials to prepare tertiary-butyl propyl ether and justify your answer.
Q31
short answer
1 mark
Give the IUPAC name of the above mentioned ether.
Q32
short answer
3 marks
(i) Allyl chloride is hydrolysed more readily than n-propyl chloride.
Q33
short answer
3 marks
(ii) Isocyanides are formed when alkyl halides are treated with silver cyanide.
Q34
short answer
3 marks
(iii) Methyl chloride reacts faster with – OH ion in SN2 reaction than t-butyl chloride.
Q35
short answer
3 marks
(b) Complete the following reactions by writing the structural formulae of ‘A’ and ‘B’ : (i) CH3CH = CH2 HBr Peroxide → ‘A’ aq. KOH → ‘B’ (ii) CH3CH2CHCH3 alc. KOH → ‘A’ HBr → ‘B’ | Cl (iii) ‘A’ Mg → CH3CH2MgCl HO2 H →+ ‘B’ (Main product)
Q36
short answer
2 marks
(a) Can sodium propoxide and t-butyl chloride be used for the preparation of t-butyl propyl ether ? Give suitable explanation. Justify your answer by suggesting the appropriate starting material required for the preparation of t-butyl propyl ether.
Reading Passage
According to the generally accepted definition of the ideal solution there are equal interaction forces acting between molecules belonging to the same or different species. (This is equivalent to the statement that the activity of the components equals the concentration.) Strictly speaking, this condition is fulfilled only in exceptional cases for mixtures (optical isomers, isotopic mixtures of an element, hydrocarbon mixtures). It is still usual to talk about ideal solutions as limiting cases in reality since very dilute solutions behave ideally with respect to the solvent. This view is further supported by the fact that Raoult’s law empirically found for describing the behaviour of the solvent in dilute solutions can be deduced thermodynamically via the assumption of ideal behaviour of the solvent.
Q39
short answer
2 marks
Give one example of miscible liquid pair which shows negative deviation from Raoult’s law. What is the reason for such deviation ?
Q40
short answer
1 mark
State Raoult’s law for a solution containing volatile components.
Q41
short answer
1 mark
Raoult’s law is a special case of Henry’s law. Comment.
Q42
short answer
1 mark
Write two characteristics of an ideal solution.
Reading Passage
Ribose and 2-deoxyribose have an important role in biology. Among the most important derivatives are those with phosphate groups attached at the 5 position. Mono-, di- and tri-phosphate forms are important, as well as 3-5 cyclic monophosphates. Purines and pyrimidines form an important class of compounds with ribose and deoxyribose. When these purine and pyrimidine derivatives are coupled to a ribose sugar, they are called nucleosides.
Q43
short answer
2 marks
What products would be formed when DNA is hydrolysed ? How is DNA different from RNA with reference to a structure ?
Q44
short answer
1 mark
Differentiate between nucleotide and nucleoside.
Q45
short answer
1 mark
Mention two important functions of nucleic acid.
Q46
short answer
1 mark
Name the linkage which joins two nucleotides. Name the base that is found in nucleotide of RNA but not in DNA.
Q47
short answer
3 marks
(I) [Ni(CO)4] is diamagnetic whereas [NiCl4]2– is paramagnetic. [Atomic number : Ni = 28] (II) CO is a stronger complexing agent than NH3. (III) The trans isomer of complex [Co(en)2Cl2]+ is optically inactive.
Q48
short answer
2 marks
Using Crystal Field theory, write the number of unpaired electrons in octahedral complexes of Fe3+ in the presence of : (I) Strong field ligand (II) Weak field ligand [Atomic number : Fe = 26]
Q49
short answer
3 marks
Name the type of isomerism exhibited by the following compounds. Also draw their corresponding isomers. (I) [Co(NH3)6] [Cr(CN)6] (II) [Co(en)3]3+ (III) [Co(NH3)3(NO2)3]
Q50
short answer
2 marks
Differentiate between weak field and strong field ligands. How does the strength of the ligand influence the spin of the complex ?
Q51
short answer
3 marks
The initial concentration of N2O5 in the first order reaction: N2O5(g) → 2NO2(g) + 1/2 O2(g) was 1.2 x 10–2 mol L–1. The concentration of N2O5 after 60 minutes was 0.2 x 10–2 mol L–1. Calculate the rate constant of the reaction at 318 K. [log 6 = 0.778]
Q52
short answer
2 marks
Account for the following : (I) We cannot determine the order of a reaction by taking into consideration the balanced chemical equation. (II) A bimolecular reaction may become kinetically of first order under a specified condition.
Q53
short answer
3 marks
The rate of the chemical reaction doubles for an increase of 10 K in absolute temperature from 298 K. Calculate activation energy (Ea). [2.303 R = 19.15 JK–1 mol–1, log 2 = 0.3]
Q54
short answer
2 marks
For a reaction: 2H2O2 —I–→ 2H2O + O2, the proposed mechanism is as given below: (I) H2O2 + I– → H2O + IO– (slow) (II) H2O2 + IO– → H2O + I– + O2 (fast) (1) Write rate law for the reaction. (2) Write the overall order and molecularity of the reaction.
Q55
short answer
3 marks
Complete the following reactions by writing the structure of the main products: (I), (II) (CH3)2Cd + 2CH3COCl →, (III).
Q56
short answer
2 marks
Give simple chemical test to distinguish between the following pairs of compounds: (I) Ethyl benzoate and benzoic acid (II) Propanal and propanone
Q57
short answer
3 marks
Complete each synthesis by giving missing starting material, reagent or products: (I), (II), (III).
Q58
short answer
2 marks
Carry out the following conversions: (I) Benzaldehyde to Benzophenone (II) Benzaldehyde to 3-phenyl propanol