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Chapter 12: Basic concepts of organic reactions — Online MCQ Test

CHEMISTRY · CLASS 11th · Tamil Nadu State Board

Practice Chapter 12: Basic concepts of organic reactions with a free chapter-wise online MCQ test for Tamil Nadu State Board CLASS 11th CHEMISTRY. This chapter covers: Focusing on reaction mechanisms this chapter details covalent bond cleavage inductive electromeric resonance and hyperconjugation effects. Students examine electrophiles nucleophil.... AI-generated questions from basic to board-exam level, with instant results and explanations.

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Chapter 12: Basic concepts of organic reactions — Important Questions & Answers (FAQ)

Frequently asked questions from Tamil Nadu State Board CLASS 11th CHEMISTRY — Chapter 12: Basic concepts of organic reactions, with answers and explanations. These are sample questions; the exam has its own separate question set.

Which of the following species acts as an electrophile?
  • A. NH3
  • B. BF3 ✓
  • C. H2O
  • D. ROH
Answer: B. BF3
BF3 is an electron-deficient molecule with an incomplete octet, making it a Lewis acid or electrophile.
The permanent displacement of a shared pair of electrons in a carbon chain due to the difference in electronegativity is called:
  • A. Electromeric effect
  • B. Inductive effect ✓
  • C. Hyperconjugation
  • D. Resonance
Answer: B. Inductive effect
Inductive effect is the permanent displacement of sigma electrons along a chain due to electronegativity differences.
Which effect is a temporary electronic effect?
  • A. Inductive effect
  • B. Resonance
  • C. Electromeric effect ✓
  • D. Hyperconjugation
Answer: C. Electromeric effect
Electromeric effect operates only in the presence of an attacking reagent and vanishes when the reagent is removed.
Which of the following pairs represents resonance structures?
  • A. CH3-CH2-OH and CH3-O-CH3
  • B. CH2=CH-CH=O and -CH2-CH=CH-O+ ✓
  • C. CH3-COOH and CH3-COO-
  • D. CH3-CH2-CH3 and CH3-CH2-CH2-CH3
Answer: B. CH2=CH-CH=O and -CH2-CH=CH-O+
Resonance structures involve the shift of pi or lone pair electrons without changing atomic positions.
In the reaction CH3-CH2-Br + OH- -> CH3-CH2-OH + Br-, the OH- ion acts as a:
  • A. Electrophile
  • B. Nucleophile ✓
  • C. Free radical
  • D. Lewis acid
Answer: B. Nucleophile
The hydroxide ion donates an electron pair to the carbon atom, acting as a nucleophile.

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